In this work, we present the efficent synthesis of two novel

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steriods Cyanosubstituted polyphenylene vinylenes (PPVs) have been in the focus of research for several decades due to their interesting optoelectronic properties and potential applications in organic electronics. With the advent of organic twodimensional (2D) crystals, the question arose how the chemical and optoelectronic advantages of PPVs evolve in 2D compared to their linear counterparts. In this work, we present the efficent synthesis of two novel 2D fully spcarbonlinked crystalline PPVs and investigate the essentiality of inorganic bases for their catalytic formation. steriods

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